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Chemoselective palladium-catalyzed deprotonative arylation/[1,2]-Wittig rearrangement of pyridylmethyl ethers

Control of chemoselectivity is one of the most challenging problems facing chemists and is particularly important in the synthesis of bioactive compounds and medications. Herein, the first highly chemoselective tandem C(sp(3))–H arylation/[1,2]-Wittig rearrangement of pyridylmethyl ethers is present...

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Publicado en:Chem Sci
Main Authors: Gao, Feng, Kim, Byeong-Seon, Walsh, Patrick J.
Formato: Artigo
Idioma:Inglês
Publicado: Royal Society of Chemistry 2016
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC4800319/
https://ncbi.nlm.nih.gov/pubmed/27014434
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02739j
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