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Chemoselective palladium-catalyzed deprotonative arylation/[1,2]-Wittig rearrangement of pyridylmethyl ethers

Control of chemoselectivity is one of the most challenging problems facing chemists and is particularly important in the synthesis of bioactive compounds and medications. Herein, the first highly chemoselective tandem C(sp(3))–H arylation/[1,2]-Wittig rearrangement of pyridylmethyl ethers is present...

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Publicat a:Chem Sci
Autors principals: Gao, Feng, Kim, Byeong-Seon, Walsh, Patrick J.
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2016
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4800319/
https://ncbi.nlm.nih.gov/pubmed/27014434
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02739j
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