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Chemoselective palladium-catalyzed deprotonative arylation/[1,2]-Wittig rearrangement of pyridylmethyl ethers

Control of chemoselectivity is one of the most challenging problems facing chemists and is particularly important in the synthesis of bioactive compounds and medications. Herein, the first highly chemoselective tandem C(sp(3))–H arylation/[1,2]-Wittig rearrangement of pyridylmethyl ethers is present...

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Vydáno v:Chem Sci
Hlavní autoři: Gao, Feng, Kim, Byeong-Seon, Walsh, Patrick J.
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2016
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4800319/
https://ncbi.nlm.nih.gov/pubmed/27014434
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02739j
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