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How bulky ligands control the chemoselectivity of Pd-catalyzed N-arylation of ammonia
Steric bulk has been recognized as a central design principle for supporting ligands in the widely utilized Buchwald–Hartwig amination. In a recent example, it was shown that a Pd-catalyst carrying a phosphine ligand can successfully aminate aryl halides using ammonia as the nitrogen source. Interes...
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| Udgivet i: | Chem Sci |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
The Royal Society of Chemistry
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8145866/ https://ncbi.nlm.nih.gov/pubmed/34084357 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03095f |
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