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Temperature-Dependent Reactivity of a Non-heme Fe(III)(OH)(SR) Complex: Relevance to Isopenicillin N Synthase

Non-heme iron complexes with cis-Fe(III)(OH)(SAr/OAr) coordination were isolated and examined for their reactivity with a tertiary carbon radical. The sulfur-ligated complex shows a temperature dependence on ·OH versus ArS transfer, whereas the oxygen-ligated complex does not. These results provide...

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Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:J Am Chem Soc
Egile Nagusiak: Yadav, Vishal, Siegler, Maxime A., Goldberg, David P.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2020
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC8130865/
https://ncbi.nlm.nih.gov/pubmed/33356198
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c09688
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