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Temperature-Dependent Reactivity of a Non-heme Fe(III)(OH)(SR) Complex: Relevance to Isopenicillin N Synthase
Non-heme iron complexes with cis-Fe(III)(OH)(SAr/OAr) coordination were isolated and examined for their reactivity with a tertiary carbon radical. The sulfur-ligated complex shows a temperature dependence on ·OH versus ArS transfer, whereas the oxygen-ligated complex does not. These results provide...
Gorde:
| Argitaratua izan da: | J Am Chem Soc |
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| Egile Nagusiak: | , , |
| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
2020
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8130865/ https://ncbi.nlm.nih.gov/pubmed/33356198 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c09688 |
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