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Dioxygen-Derived Nonheme Mononuclear Fe(III)(OH) Complex and Its Reactivity with Carbon Radicals
A new tetradentate, monoanionic, mixed N/O donor ligand (BNPA(Ph2)O(−)) with second coordination sphere H-bonding groups has been synthesized for stabilization of terminal Fe(III)(OH)(X) complexes. The complex [Fe(II)(BNPA(Ph2)O)(OTf)] (1) reacts with O(2) to give a mononuclear terminal Fe(III)(OH)...
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| Publicado en: | J Am Chem Soc |
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| Autores principales: | , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2019
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8006860/ https://ncbi.nlm.nih.gov/pubmed/31244183 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b03329 |
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