Observation of Radical Rebound in a Mononuclear Nonheme Iron Model Complex

A nonheme iron(III) terminal methoxide complex, [Fe(III)(N3PyO(2Ph))(OCH(3))]ClO(4), was synthesized. Reaction of this complex with the triphenylmethyl radical (Ph(3)C•) leads to formation of Ph(3)COCH(3) and the one-electron reduced iron(II) center, as seen by UV-vis, EPR, (1)H NMR, and Mössbauer s...

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Bibliographic Details
Published in:J Am Chem Soc
Main Authors: Pangia, Thomas M., Davies, Casey G., Prendergast, Joshua R., Gordon, Jesse B., Siegler, Maxime A., Jameson, Guy N. L., Goldberg, David P.
Format: Artigo
Language:Inglês
Published: 2018
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6047074/
https://ncbi.nlm.nih.gov/pubmed/29537258
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b12707
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