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Observation of Radical Rebound in a Mononuclear Nonheme Iron Model Complex
A nonheme iron(III) terminal methoxide complex, [Fe(III)(N3PyO(2Ph))(OCH(3))]ClO(4), was synthesized. Reaction of this complex with the triphenylmethyl radical (Ph(3)C•) leads to formation of Ph(3)COCH(3) and the one-electron reduced iron(II) center, as seen by UV-vis, EPR, (1)H NMR, and Mössbauer s...
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| Pubblicato in: | J Am Chem Soc |
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| Autori principali: | , , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2018
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6047074/ https://ncbi.nlm.nih.gov/pubmed/29537258 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b12707 |
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