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Structures, spectroscopic properties, and dioxygen reactivity of 5- and 6-coordinate nonheme iron(II) complexes: a combined enzyme/model study of thiol dioxygenases
The synthesis of four new Fe(II)(N(4)S(thiolate)) complexes as models of the thiol dioxygenases are described. They are composed of derivatives of the neutral, tridentate ligand triazacyclononane (R(3)TACN; R = Me, iPr) and 2-aminobenzenethiolate (abt(x); X = H, CF(3)), a non-native substrate for cy...
Tallennettuna:
| Julkaisussa: | J Am Chem Soc |
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| Päätekijät: | , , , , , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
2018
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6596423/ https://ncbi.nlm.nih.gov/pubmed/30346746 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b08349 |
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