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Structures, spectroscopic properties, and dioxygen reactivity of 5- and 6-coordinate nonheme iron(II) complexes: a combined enzyme/model study of thiol dioxygenases
The synthesis of four new Fe(II)(N(4)S(thiolate)) complexes as models of the thiol dioxygenases are described. They are composed of derivatives of the neutral, tridentate ligand triazacyclononane (R(3)TACN; R = Me, iPr) and 2-aminobenzenethiolate (abt(x); X = H, CF(3)), a non-native substrate for cy...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6596423/ https://ncbi.nlm.nih.gov/pubmed/30346746 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b08349 |
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