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Determining the Inherent Selectivity for Carbon Radical Hydroxylation versus Halogenation with Fe(III)(OH)(X) Complexes: Relevance to the Rebound Step in Non-heme Iron Halogenases
The first structural models of the proposed cis-Fe(III)(OH)(halide) intermediate in the non-heme iron halogenases were synthesized and examined for their inherent reactivity with tertiary carbon radicals. Selective hydroxylation occurs for these cis-Fe(III)(OH)(X) (X = Cl, Br) complexes in a radical...
Gardado en:
| Publicado en: | J Am Chem Soc |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2020
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8177055/ https://ncbi.nlm.nih.gov/pubmed/32281794 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c00493 |
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