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C(sp(3))–H methylation enabled by peroxide photosensitization and Ni-mediated radical coupling

The “magic methyl” effect describes the change in potency, selectivity, and/or metabolic stability of a drug candidate associated with addition of a single methyl group. Here, we report a synthetic method that enables direct methylation of C(sp(3))–H bonds in diverse drug-like molecules and pharmace...

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Detalhes bibliográficos
Publicado no:Science
Main Authors: Vasilopoulos, Aristidis, Krska, Shane W., Stahl, Shannon S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8110093/
https://ncbi.nlm.nih.gov/pubmed/33888639
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.abh2623
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