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Direct C(sp(3))–H Cross Coupling Enabled by Catalytic Generation of Chlorine Radicals

Here we report the development of a C(sp(3))–H cross-coupling platform enabled by the catalytic generation of chlorine radicals by nickel and photoredox catalysis. Aryl chlorides serve as both cross-coupling partners and the chlorine radical source for the α-oxy C(sp(3))–H arylation of cyclic and ac...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Shields, Benjamin J., Doyle, Abigail G.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5215658/
https://ncbi.nlm.nih.gov/pubmed/27653738
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b08397
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