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Ligand-Enabled Cross-Coupling of C(sp(3))–H Bonds with Arylsilanes

Pd(II)-catalyzed cross-coupling of C(sp(3))–H bonds with organosilicon coupling partners has been achieved for the first time. The use of a newly developed quinoline-based ligand is essential for the cross-coupling reactions to proceed.

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: He, Jian, Takise, Ryosuke, Fu, Haiyan, Yu, Jin-Quan
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4432906/
https://ncbi.nlm.nih.gov/pubmed/25822198
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b00890
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