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Ligand-Enabled Alkynylation of C(sp(3))–H Bonds with Pd(II) Catalysts()
The palladium(II)-catalyzed β- and γ-alkynylation of C(sp(3))−H bonds of amides enabled by pyridine-based ligands has been developed. This alkynylation reaction is compatible with substrates containing α-tertiary or α-quaternary carbon centers. The β-methylene C(sp(3))−H bonds in various carbocyclic...
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| Publicado en: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2017
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5512278/ https://ncbi.nlm.nih.gov/pubmed/28078773 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201610426 |
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