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Ligand-Enabled Methylene C(sp(3))–H Bond Activation with A Pd(II) Catalyst
Pd(II)-Insertion into β-methylene C(sp(3))–H bonds was enabled by a mutually-repulsive and electron-rich quinoline ligand. Ligand tuning has led to the development of a method that allows for installation of an aryl group on a range of acyclic and cyclic amides containing β-methylene C(sp(3))–H bond...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3500088/ https://ncbi.nlm.nih.gov/pubmed/23116159 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja309325e |
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