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Direct C(sp(3))–H Cross Coupling Enabled by Catalytic Generation of Chlorine Radicals
Here we report the development of a C(sp(3))–H cross-coupling platform enabled by the catalytic generation of chlorine radicals by nickel and photoredox catalysis. Aryl chlorides serve as both cross-coupling partners and the chlorine radical source for the α-oxy C(sp(3))–H arylation of cyclic and ac...
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2016
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5215658/ https://ncbi.nlm.nih.gov/pubmed/27653738 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b08397 |
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