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Copper-catalysed benzylic C–H coupling with alcohols via radical relay enabled by redox buffering

Cross-coupling reactions enable rapid, convergent synthesis of diverse molecules and provide the foundation for modern chemical synthesis. The most widely used methods employ sp(2)-hybridized coupling partners, such as aryl halides or related pre-functionalized substrates. Here, we demonstrate coppe...

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Detalhes bibliográficos
Publicado no:Nat Catal
Main Authors: Hu, Huayou, Chen, Si-Jie, Mandal, Mukunda, Pratik, Saied Md, Buss, Joshua A., Krska, Shane W., Cramer, Christopher J., Stahl, Shannon S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7197765/
https://ncbi.nlm.nih.gov/pubmed/32368720
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41929-020-0425-1
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