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Site-Selective Copper-Catalyzed Azidation of Benzylic C─H Bonds
Site selectivity represents a key challenge for nondirected C─H functionalization, even when the C─H bond is intrinsically reactive. Here, we report a copper-catalyzed method for benzylic C─H azidation of diverse molecules. Experimental and density functional theory studies suggest the benzyl radica...
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| Publicat a: | J Am Chem Soc |
|---|---|
| Autors principals: | , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2020
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7405889/ https://ncbi.nlm.nih.gov/pubmed/32539355 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c05362 |
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