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Site-Selective Copper-Catalyzed Azidation of Benzylic C─H Bonds
Site selectivity represents a key challenge for nondirected C─H functionalization, even when the C─H bond is intrinsically reactive. Here, we report a copper-catalyzed method for benzylic C─H azidation of diverse molecules. Experimental and density functional theory studies suggest the benzyl radica...
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| Veröffentlicht in: | J Am Chem Soc |
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| Hauptverfasser: | , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2020
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7405889/ https://ncbi.nlm.nih.gov/pubmed/32539355 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c05362 |
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