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SYNTHESIS AND ENANTIOSELECTIVITY OF CYCLOPROPAVIR PHOSPHATES FOR CELLULAR GMP KINASE

Enantiomeric cyclopropavir phosphates (+)-9 and (−)-9 were synthesized and investigated as substrates for GMP kinase. N(2)-Isobutyryl-di-O-acetylcyclopropavir (11) was converted to (+)-monoacetate 12 using hydrolysis catalyzed by porcine liver esterase. Phosphorylation via phosphite 13 gave after de...

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Bibliographische Detailangaben
Veröffentlicht in:Nucleosides Nucleotides Nucleic Acids
Hauptverfasser: Li, Chengwei, Gentry, Brian G., Drach, John C., Zemlicka, Jiri
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2009
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7976111/
https://ncbi.nlm.nih.gov/pubmed/20183619
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1080/15257770903172720
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