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Enantioselective Addition of α-Nitroesters to Alkynes
By using Rh-H catalysis, we couple α-nitroesters and alkynes to prepare α-amino acid precursors. This atom-economical strategy generates two contiguous stereocenters, with high enantio- and diastereocontrol. In this transformation, the alkyne undergoes isomerization to generate a Rh(III)-π-allyl ele...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2021
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7927945/ https://ncbi.nlm.nih.gov/pubmed/33411337 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202014015 |
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