Wordt geladen...
Enantioselective Addition of α-Nitroesters to Alkynes
By using Rh-H catalysis, we couple α-nitroesters and alkynes to prepare α-amino acid precursors. This atom-economical strategy generates two contiguous stereocenters, with high enantio- and diastereocontrol. In this transformation, the alkyne undergoes isomerization to generate a Rh(III)-π-allyl ele...
Bewaard in:
| Gepubliceerd in: | Angew Chem Int Ed Engl |
|---|---|
| Hoofdauteurs: | , , , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2021
|
| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7927945/ https://ncbi.nlm.nih.gov/pubmed/33411337 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202014015 |
| Tags: |
Voeg label toe
Geen labels, Wees de eerste die dit record labelt!
|