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Catalytic Hydrothiolation: Regio- and Enantioselective Coupling of Thiols and Dienes
We report a Rh-catalyzed hydrothiolation of 1,3-dienes, including petroleum feedstocks. Either secondary or tertiary allylic sulfides can be generated from the selective addition of a thiol to the more substituted double bond of a diene. The catalyst tolerates a wide range of functional groups, and...
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| Veröffentlicht in: | J Am Chem Soc |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6563822/ https://ncbi.nlm.nih.gov/pubmed/30091909 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b06957 |
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