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Rhodium-Catalyzed Hydrofunctionalization: Enantioselective Coupling of Indolines and 1,3-Dienes
We communicate a strategy for the hydrofunctionalization of 1,3-dienes via Rh-hydride catalysis. Conjugated dienes are coupled to nucleophiles to demonstrate the feasibility of novel C–C, C–O, C–S, and C–N bond forming processes. In the presence of a chiral JoSPOphos ligand, hydroamination generates...
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| Izdano u: | J Am Chem Soc |
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| Glavni autori: | , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2017
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6857534/ https://ncbi.nlm.nih.gov/pubmed/28128936 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b12307 |
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