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Rhodium-Catalyzed Enantioselective Hydroamination of Alkynes with Indolines
The hydroamination of internal alkynes via tandem rhodium-catalysis gives branched N-allylic indolines with high regio- and enantioselectivity. An acid-switch provides access to the linear isomer in preference to the branched isomer by an isomerization mechanism. Mechanistic studies suggest formatio...
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| Pubblicato in: | J Am Chem Soc |
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| Autori principali: | , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2015
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4870006/ https://ncbi.nlm.nih.gov/pubmed/26107923 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b05200 |
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