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Rhodium-Catalyzed Enantioselective Hydroamination of Alkynes with Indolines

The hydroamination of internal alkynes via tandem rhodium-catalysis gives branched N-allylic indolines with high regio- and enantioselectivity. An acid-switch provides access to the linear isomer in preference to the branched isomer by an isomerization mechanism. Mechanistic studies suggest formatio...

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Bibliografiske detaljer
Udgivet i:J Am Chem Soc
Main Authors: Chen, Qing-An, Chen, Zhiwei, Dong, Vy M.
Format: Artigo
Sprog:Inglês
Udgivet: 2015
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4870006/
https://ncbi.nlm.nih.gov/pubmed/26107923
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b05200
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