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Cationic Co(I)-Intermediates for Hydrofunctionalization Reactions: Regio- and Enantioselective Cobalt-Catalyzed 1,2-Hydroboration of 1,3- Dienes

Much of the recent work on catalytic hydroboration of alkenes has focused on simple alkenes and styrene derivatives with few examples of reactions of 1,3- dienes, which have been reported to undergo mostly 1,4- additions to give allylic boronates. We find that reduced cobalt catalysts generated from...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Duvvuri, Krishnaja, Dewese, Kendra R., Parsutkar, Mahesh M., Jing, Stanley M., Mehta, Milauni M., Gallucci, Judith C., RajanBabu, T. V.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6528837/
https://ncbi.nlm.nih.gov/pubmed/31020835
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b13812
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