Cargando...
Cobalt-catalysed asymmetric hydrovinylation of 1,3-dienes
In the presence of bidentate 1,n-bis-diphenylphosphinoalkane-CoCl(2) complexes {Cl(2)Co[P ∼ P]} and Me(3)Al or methylaluminoxane, acyclic (E)-1,3-dienes react with ethylene (1 atmosphere) to give excellent yields of hydrovinylation products. The regioselectivity (1,4- or 1,2-addition) and the alkene...
Guardado en:
| Publicado en: | Chem Sci |
|---|---|
| Autores principales: | , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
Royal Society of Chemistry
2015
|
| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4587399/ https://ncbi.nlm.nih.gov/pubmed/26430505 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc00929d |
| Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|