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Chemoselective Reactions of (E)-1,3-Dienes: Cobalt-Mediated Isomerization to (Z)-1,3-Dienes and Reactions with Ethylene
[Image: see text] In the asymmetric hydrovinylation (HV) of an E/Z-mixture of a prototypical 1,3-diene with (S,S)-(DIOP)CoCl(2) or (S,S)-(BDPP)CoCl(2) catalyst in the presence of Me(3)Al, the (E)-isomer reacts significantly faster, leaving behind the Z-isomer intact at the end of the reaction. The p...
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| Autors principals: | , , |
|---|---|
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
American Chemical
Society
2014
|
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4046774/ https://ncbi.nlm.nih.gov/pubmed/24712838 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja501979g |
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