Regio- and Enantioselective Catalytic Monoepoxidation of Conjugated Dienes: Synthesis of Chiral Allylic cis-Epoxides

[Image: see text] Ti(IV)-salan 4 catalyzes the diastereo- and enantioselective monoepoxidation of conjugated dienes using 30% H(2)O(2) at rt or below even in the presence of other olefins and adjacent stereocenters. Its enantiomer, ent-4, provides access to the opposite diastereomer or enantiomer. T...

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Udgivet i:Org Lett
Main Authors: Jat, Jawahar L., De, Saroj Ranjan, Kumar, Ganesh, Adebesin, Adeniyi Michael, Gandham, Shyam K., Falck, John R.
Format: Artigo
Sprog:Inglês
Udgivet: American Chemical Society 2015
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4342986/
https://ncbi.nlm.nih.gov/pubmed/25668127
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.5b00281
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