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Regio- and Stereoselective Monoepoxidation of Dienes using Methyltrioxorhenium: Synthesis of Allylic Epoxides
[Image: see text] Methyltrioxorhenium (MTO) complexed with pyridine was shown to be a highly effective catalyst for the regioselective monoepoxidation of conjugated di- and trienes using 30% H(2)O(2) at or below room temperature. The resultant allylic epoxides, and the triols derived from them, are...
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| Gepubliceerd in: | J Org Chem |
|---|---|
| Hoofdauteurs: | , , , , , , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
American Chemical
Society
2014
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| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4227570/ https://ncbi.nlm.nih.gov/pubmed/25321319 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo501958d |
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