Regio- and Stereoselective Monoepoxidation of Dienes using Methyltrioxorhenium: Synthesis of Allylic Epoxides

[Image: see text] Methyltrioxorhenium (MTO) complexed with pyridine was shown to be a highly effective catalyst for the regioselective monoepoxidation of conjugated di- and trienes using 30% H(2)O(2) at or below room temperature. The resultant allylic epoxides, and the triols derived from them, are...

Description complète

Enregistré dans:
Détails bibliographiques
Publié dans:J Org Chem
Auteurs principaux: De, Saroj Ranjan, Kumar, Ganesh, Jat, Jawahar L., Birudaraju, Saritha, Lu, Biao, Manne, Rajkumar, Puli, Narender, Adebesin, Adeniyi Michael, Falck, John R.
Format: Artigo
Langue:Inglês
Publié: American Chemical Society 2014
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4227570/
https://ncbi.nlm.nih.gov/pubmed/25321319
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo501958d
Tags: Ajouter un tag
Pas de tags, Soyez le premier à ajouter un tag!

Documents similaires