Regio- and Stereoselective Monoepoxidation of Dienes using Methyltrioxorhenium: Synthesis of Allylic Epoxides

[Image: see text] Methyltrioxorhenium (MTO) complexed with pyridine was shown to be a highly effective catalyst for the regioselective monoepoxidation of conjugated di- and trienes using 30% H(2)O(2) at or below room temperature. The resultant allylic epoxides, and the triols derived from them, are...

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Detalhes bibliográficos
Publicado no:J Org Chem
Main Authors: De, Saroj Ranjan, Kumar, Ganesh, Jat, Jawahar L., Birudaraju, Saritha, Lu, Biao, Manne, Rajkumar, Puli, Narender, Adebesin, Adeniyi Michael, Falck, John R.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4227570/
https://ncbi.nlm.nih.gov/pubmed/25321319
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo501958d
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