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Enantioselective Epoxidation of Non-conjugated cis-Olefins by Chiral Dioxirane
[Image: see text] A variety of non-conjugated cis-olefins has been enantioselectively epoxidized with chiral ketones 2, and up to 92% ee has been obtained. The two prochiral faces of an olefin are likely stereodifferentiated by the relative hydrophobicity of the olefin substituents and/or allylic ox...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2783705/ https://ncbi.nlm.nih.gov/pubmed/19824657 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol901724v |
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