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A Diacetate Ketone-Catalyzed Asymmetric Epoxidation of Olefins
[Image: see text] A fructose-derived diacetate ketone has been shown to be an effective catalyst for asymmetric epoxidation. High ee’s have been obtained for a variety of trans- and trisubstituted olefins including electron-deficient α,β-unsaturated esters as well as certain cis-olefins.
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2009
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2749516/ https://ncbi.nlm.nih.gov/pubmed/19388627 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo900330n |
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