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Enantioselective Epoxidation of Non-conjugated cis-Olefins by Chiral Dioxirane

[Image: see text] A variety of non-conjugated cis-olefins has been enantioselectively epoxidized with chiral ketones 2, and up to 92% ee has been obtained. The two prochiral faces of an olefin are likely stereodifferentiated by the relative hydrophobicity of the olefin substituents and/or allylic ox...

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Sparad:
Bibliografiska uppgifter
Huvudupphovsmän: Burke, Christopher P., Shi, Yian
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2009
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC2783705/
https://ncbi.nlm.nih.gov/pubmed/19824657
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol901724v
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