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Enantioselective Epoxidation of Non-conjugated cis-Olefins by Chiral Dioxirane
[Image: see text] A variety of non-conjugated cis-olefins has been enantioselectively epoxidized with chiral ketones 2, and up to 92% ee has been obtained. The two prochiral faces of an olefin are likely stereodifferentiated by the relative hydrophobicity of the olefin substituents and/or allylic ox...
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| Hlavní autoři: | , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2009
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2783705/ https://ncbi.nlm.nih.gov/pubmed/19824657 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol901724v |
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