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Regio- and Enantioselective Catalytic Monoepoxidation of Conjugated Dienes: Synthesis of Chiral Allylic cis-Epoxides
[Image: see text] Ti(IV)-salan 4 catalyzes the diastereo- and enantioselective monoepoxidation of conjugated dienes using 30% H(2)O(2) at rt or below even in the presence of other olefins and adjacent stereocenters. Its enantiomer, ent-4, provides access to the opposite diastereomer or enantiomer. T...
Shranjeno v:
| izdano v: | Org Lett |
|---|---|
| Main Authors: | , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
American
Chemical Society
2015
|
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4342986/ https://ncbi.nlm.nih.gov/pubmed/25668127 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.5b00281 |
| Oznake: |
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