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Enantioselective Coupling of Dienes and Phosphine Oxides
We report a Pd-catalyzed intermolecular hydrophosphinylation of 1,3-dienes to afford chiral allylic phosphine oxides. Commodity dienes and air stable phosphine oxides couple to generate organophosphorus building blocks with high enantio- and regiocontrol. This method constitutes the first asymmetric...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6607437/ https://ncbi.nlm.nih.gov/pubmed/30451496 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b11150 |
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