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Access to P-chiral phosphine oxides by enantioselective allylic alkylation of bisphenols
A novel biscinchona alkaloid-catalyzed highly enantioselective desymmetrization reaction of bisphenol compounds with achiral Morita–Baylis–Hillman carbonate agents was developed. Through the asymmetric allylic alkylation strategy, a broad range of optically active P-stereogenic phosphine oxides were...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6499109/ https://ncbi.nlm.nih.gov/pubmed/31105926 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc05439h |
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