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Iridium-catalyzed enantioselective direct vinylogous allylic alkylation of coumarins
The first iridium-catalyzed enantioselective vinylogous allylic alkylation of coumarins is presented. Using easily accessible linear allylic carbonates as the allylic electrophile, this reaction installs unfunctionalized allyl groups at the γ-position of 4-methylcoumarins in an exclusively branched-...
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| Veröffentlicht in: | Chem Sci |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Royal Society of Chemistry
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6050583/ https://ncbi.nlm.nih.gov/pubmed/30079186 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc02041h |
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