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Nickel-catalyzed enantioselective allylic alkylation of lactones and lactams with unactivated allylic alcohols

The first nickel-catalyzed enantioselective allylic alkylation of lactone and lactam substrates to deliver products bearing an all-carbon quaternary stereocenter is reported. The reaction, which utilizes a commercially available chiral bisphosphine ligand, proceeds in good yield with a high level of...

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Publicat a:Chem Sci
Autors principals: Ngamnithiporn, Aurapat, Jette, Carina I., Bachman, Shoshana, Virgil, Scott C., Stoltz, Brian M.
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2018
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5912103/
https://ncbi.nlm.nih.gov/pubmed/29732133
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc05216b
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