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Nickel-catalyzed enantioselective allylic alkylation of lactones and lactams with unactivated allylic alcohols
The first nickel-catalyzed enantioselective allylic alkylation of lactone and lactam substrates to deliver products bearing an all-carbon quaternary stereocenter is reported. The reaction, which utilizes a commercially available chiral bisphosphine ligand, proceeds in good yield with a high level of...
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| Izdano u: | Chem Sci |
|---|---|
| Glavni autori: | , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
Royal Society of Chemistry
2018
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5912103/ https://ncbi.nlm.nih.gov/pubmed/29732133 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc05216b |
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