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Enantioselective synthesis of highly oxygenated acyclic quaternary center-containing building blocks via palladium-catalyzed decarboxylative allylic alkylation of cyclic siloxyketones

The development of a palladium-catalyzed enantioselective decarboxylative allylic alkylation of cyclic siloxyketones to produce enantioenriched silicon-tethered heterocycles is reported. The reaction proceeds smoothly to provide products bearing a quaternary stereocenter in excellent yields (up to 9...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Ngamnithiporn, Aurapat, Iwayama, Toshihiko, Bartberger, Michael D., Stoltz, Brian M.
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8162308/
https://ncbi.nlm.nih.gov/pubmed/34123197
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc04383d
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