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Enantioselective Iridium-Catalyzed Allylic Alkylation Reactions of Masked Acyl Cyanide Equivalents

The first enantioselective iridium-catalyzed allylic alkylation reaction of a masked acyl cyanide (MAC) reagent has been developed. The transformation allows for the use of an umpoled synthon, which serves as a carbon monoxide equivalent. The reaction proceeds with good yield and excellent selectivi...

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Dettagli Bibliografici
Pubblicato in:Org Lett
Autori principali: Hethcox, J. Caleb, Shockley, Samantha E., Stoltz, Brian M.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2017
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5470644/
https://ncbi.nlm.nih.gov/pubmed/28291366
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b00449
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