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Enantioselective Synthesis of Vicinal All-Carbon Quaternary Centers via Iridium-Catalyzed Allylic Alkylation

The development of the first enantioselective transition metal-catalyzed allylic alkylation providing access to acyclic products bearing vicinal all-carbon quaternary centers is disclosed. The iridium-catalyzed allylic alkylation reaction proceeds with excellent yields and selectivities for a range...

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書目詳細資料
發表在:Angew Chem Int Ed Engl
Main Authors: Hethcox, J. Caleb, Shockley, Samantha E., Stoltz, Brian M.
格式: Artigo
語言:Inglês
出版: 2018
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC6033654/
https://ncbi.nlm.nih.gov/pubmed/29750856
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201804820
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