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Iridium-catalyzed enantioselective olefinic C(sp(2))–H allylic alkylation
The first iridium-catalyzed enantioselective olefinic C(sp(2))–H allylic alkylation is developed in cooperation with Lewis base catalysis. This reaction, catalyzed by cinchonidine and an in situ generated cyclometalated Ir(i)/phosphoramidite complex, makes use of the latent enolate character of an α...
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| Vydáno v: | Chem Sci |
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| Hlavní autoři: | , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
The Royal Society of Chemistry
2021
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8179414/ https://ncbi.nlm.nih.gov/pubmed/34164076 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc06208a |
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