Iridium‐Catalyzed Enantioselective Intermolecular Indole C2‐Allylation

The enantioselective intermolecular C2‐allylation of 3‐substituted indoles is reported for the first time. This directing group‐free approach relies on a chiral Ir‐(P, olefin) complex and Mg(ClO(4))(2) Lewis acid catalyst system to promote allylic substitution, providing the C2‐allylated products in...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Rossi‐Ashton, James A., Clarke, Aimee K., Donald, James R., Zheng, Chao, Taylor, Richard J. K., Unsworth, William P., You, Shu‐Li
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2020
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Research Articles
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7217203/
https://ncbi.nlm.nih.gov/pubmed/32091146
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202001956
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