Iridium‐Catalyzed Enantioselective Intermolecular Indole C2‐Allylation

The enantioselective intermolecular C2‐allylation of 3‐substituted indoles is reported for the first time. This directing group‐free approach relies on a chiral Ir‐(P, olefin) complex and Mg(ClO(4))(2) Lewis acid catalyst system to promote allylic substitution, providing the C2‐allylated products in...

Descripció completa

Guardat en:
Dades bibliogràfiques
Publicat a:Angew Chem Int Ed Engl
Autors principals: Rossi‐Ashton, James A., Clarke, Aimee K., Donald, James R., Zheng, Chao, Taylor, Richard J. K., Unsworth, William P., You, Shu‐Li
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
Matèries:
Research Articles
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7217203/
https://ncbi.nlm.nih.gov/pubmed/32091146
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202001956
Etiquetes: Afegir etiqueta
Sense etiquetes, Sigues el primer a etiquetar aquest registre!

Ítems similars