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Direct, Intermolecular, Enantioselective, Iridium-Catalyzed Allylation of Carbamates to Form Carbamate-Protected, Branched Allylic Amines

[Image: see text] The direct reaction between carbamates and achiral allylic carbonates to form branched, conveniently protected primary allylic amines with high regioselectivity and enantioselectivity is reported. This process occurs without base or with 0.5 equiv K(3)PO(4) in the presence of a met...

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Detalhes bibliográficos
Main Authors: Weix, Daniel J., Marković, Dean, Ueda, Mitsuhiro, Hartwig, John F.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2740486/
https://ncbi.nlm.nih.gov/pubmed/19552468
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol901151u
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