Synthesis of Fulvene Vinyl Ethers by Gold Catalysis

Gold‐catalyzed cyclization of 1,5‐diynes with ketones as reagents and solvent provides diversely substituted vinyl ethers under mild conditions. The regioselectivity of such gold‐catalyzed cyclizations is usually controlled by the scaffold of the diyne. Herein, we report the first solvent‐controlled...

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Publicado en:Chemistry
Autores principales: Ahrens, Alexander, Schwarz, Julia, Lustosa, Danilo M., Pourkaveh, Raheleh, Hoffmann, Marvin, Rominger, Frank, Rudolph, Matthias, Dreuw, Andreas, Hashmi, A. Stephen K.
Formato: Artigo
Lenguaje:Inglês
Publicado: John Wiley and Sons Inc. 2020
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC7216831/
https://ncbi.nlm.nih.gov/pubmed/32092204
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000338
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