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Visible Light‐Enabled sp(3)‐C−H Functionalization with Chloro‐ and Bromoalkynes: Chemoselective Route to Vinylchlorides or Alkynes
An unprecedented direct atom‐economic chemo‐ and regioselective hydroalkylation of chloroalkynes and an sp(3)‐C−H alkynylation of bromoalkynes was achieved. The reaction partners are unfunctionalized ethers, alcohols, amides, and even non‐activated hydrocarbons. We found that a household fluorescent...
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| Publicado no: | Chemistry |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7756539/ https://ncbi.nlm.nih.gov/pubmed/32472581 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202001259 |
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