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Visible Light‐Enabled sp(3)‐C−H Functionalization with Chloro‐ and Bromoalkynes: Chemoselective Route to Vinylchlorides or Alkynes

An unprecedented direct atom‐economic chemo‐ and regioselective hydroalkylation of chloroalkynes and an sp(3)‐C−H alkynylation of bromoalkynes was achieved. The reaction partners are unfunctionalized ethers, alcohols, amides, and even non‐activated hydrocarbons. We found that a household fluorescent...

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Detaylı Bibliyografya
Yayımlandı:Chemistry
Asıl Yazarlar: Adak, Tapas, Hoffmann, Marvin, Witzel, Sina, Rudolph, Matthias, Dreuw, Andreas, Hashmi, A. Stephen K.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: John Wiley and Sons Inc. 2020
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756539/
https://ncbi.nlm.nih.gov/pubmed/32472581
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202001259
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