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Synthesis of a 1,3-Bridged Macrobicyclic Enyne via Chemoselective Cycloisomerization Using Palladium-catalyzed Alkyne-Alkyne Coupling

A unique intramolecular Pd-catalyzed alkyne-alkyne coupling is presented. This transformation generates a strained, 1,3-bridged, macrocyclic enyne. The process was readily executed on gram-scale, and the structure of the product was elucidated via X-ray crystallographic analysis. A mechanistic ratio...

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Bibliografski detalji
Izdano u:J Org Chem
Glavni autori: Trost, Barry M., Masters, James T., Le Vaillant, Franck, Lumb, Jean-Philip
Format: Artigo
Jezik:Inglês
Izdano: 2016
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5726859/
https://ncbi.nlm.nih.gov/pubmed/27648602
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.6b01920
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