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Rh(I)-Catalyzed Cycloisomerization of 1,6-Enynes

A new and unexpected Rh(I)-catalyzed cycloisomerization of 1,6-enynes is reported. Several different alkyne substitution patterns were evaluated under the reaction conditions, including a deuterated derivative that provides some insight into the reaction mechanism.

Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Synlett
Egile Nagusiak: Matsushima, Yuji, Phillips, Eric M., Bergman, Robert G., Ellman, Jonathan A.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2015
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC4655000/
https://ncbi.nlm.nih.gov/pubmed/26609195
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0034-1380359
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