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C–C Bond Migration in the Cycloisomerization of 1,6-Enynes()

A full account of our investigation of C–C bond migration in the cycloisomerization of oxygen-tethered 1,6-enynes is described. Under Pt(II) and/or Ir(I) catalysis, cyclic and acylic alkyl groups were found to undergo 1,2-shifts into metal carbenoid intermediates. Interestingly, this process does no...

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Detalhes bibliográficos
Publicado no:Org Chem Front
Main Authors: Stevenson, Susan M., Newcomb, Eric T., Ferreira, Eric M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5321652/
https://ncbi.nlm.nih.gov/pubmed/28239480
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C6QO00224B
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